Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
نویسندگان
چکیده
In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl-sulfoxide ligands [Cr-O = 1.970 (2)-1.972 (2) Å; O-Cr-O = 88.19 (9) and 91.81 (9)°] in a slightly distorted octa-hedral geometry. The Cl(-) anions take part in the formation of weak C-H⋯Cl hydrogen bonds, which contribute to the crystal packing stabilization.
منابع مشابه
Hexakis(dimethyl sulfoxide-κO)cobalt(III) trinitrate
The metal atom of the title salt, [Co(C(2)H(6)OS)(6)](NO(3))(3), is coordinated by six dimethyl sulfoxide mol-ecules in an octa-hedral geometry. The metal atom lies on a special position of site symmetry. One of the nitrate ions lies on a special position of 3 site symmetry and the other independent ion is disordered about a special position of site symmetry.
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